From college to graduate school, it took me years to get used to Green's function. I often wonder if it's the same case for others or am I just not too bright. GF is of course an extremely powerful method that takes many years of reading and practice until one is completely comfortable with it. Physics undergraduates probably learned about it---as I did---in a mathematics class, but it is usually unused by physics classes. For example, Griffiths' EM book---standard textbook on the subject---do not use and GF and his QM book only uses it in the scattering theory chapter (for which GF is very useful) at the very end.
My hand-waving understanding of GF is the following: it is the inverse of the Hamiltonian/Linear operator in the following sense:
with the parameter
Suppose we already know how to diagonalize .
It can have both discrete and continuous eigen-kets:
and
.
Then
is simply:
One can sandwich other sides whatever complete set you prefer to get the representation in that set, e.g.
Since is hermitian, all its eigenvalues
and
are real.
So
has singularities on the real lines. It is otherwise analytic. The poles of
therefore gives discrete eigenvalues of
.
On
where
belong to the continuous spectrum of
,
the second term is not well defined since the integrand has a pole. Usually if the eigenstates associated with the continuous spectrum are propagating or extended (do not decay fast), the side limits of
as
exist but are different on both side. Let
Obviously
Using the identity
and taking the trace of
The imaginary part of
So there are physical quantities encoded in the Green's function after all. Finally
can be expressed by the discontinuity in a Kramers-Kronig-like relation:
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